I have a unicycle with a Surly Endomorph 26"x3.7" tire, and I've discovered that this tire rides best at significantly lower pressure than smaller tires.
Even though I weigh ~110 kilos, I can ride this 3.7" tire at 12psi without pinch flats.
Previously I rode a 24"x2" Nokian tire that required at least 40psi.
Is there some known relationship where higher tire volume encourages lower tire pressure?